{"id":2364,"date":"2024-08-19T14:40:25","date_gmt":"2024-08-19T06:40:25","guid":{"rendered":"http:\/\/www.bdmaee.cn\/?p=2364"},"modified":"2024-08-19T14:40:25","modified_gmt":"2024-08-19T06:40:25","slug":"%e6%9c%89%e6%9c%ba%e9%94%8c","status":"publish","type":"post","link":"http:\/\/www.bdmaee.cn\/archives\/2364","title":{"rendered":"\u6709\u673a\u950c"},"content":{"rendered":"

\u6709\u673a\u950c<\/strong><\/a><\/p>\n

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<\/p>\n

1.\u6c27\u5316\u52a0\u6210\u3002\u65e9\u7531Frankland\u53d1\u73b0\u7684\u4e8c\u4e59\u57fa\u950c\u5373\u662f\u7528\u8be5\u6cd5\u5236\u5907\uff1a\u5728\u6c22\u6c14\u7684\u201c\u4fdd\u62a4\u201d\u4e0b\uff0c\u5c06\u7898\u4e59\u70f7\u548c\u5355\u8d28\u950c\u8fdb\u884c\u52a0\u6210\u53cd\u5e94\uff08\u8be5\u53cd\u5e94\u8fd8\u79f0\u4e3a\uff1aFrankland synthesis\uff09\u3002\u91d1\u5c5e\u950c\u7684\u6d3b\u6027\u53ef\u4ee5\u901a\u8fc7Rieke\u950c\uff08Rieke zinc\uff09\u8bd5\u5242\u5f97\u5230\u589e\u5f3a\uff0c\u800c\u8be5\u8bd5\u5242\u662f\u91d1\u5c5e\u94be\u548c\u6c2f\u5316\u950c\u53d1\u751f\u8fd8\u539f\u53cd\u5e94\u5f97\u5230\u7684\u3002<\/p>\n

2RI + 2Zn \u2192 ZnR2 + ZnI2<\/p>\n

<\/p>\n

2.\u5364\u950c\u4ea4\u6362\u3002\u8be5\u6cd5\u4e3b\u8981\u5206\u4e3a\u4e24\u79cd\uff1a\u4e3a\u7898\u950c\u4ea4\u6362\u548c\u787c\u950c\u4ea4\u6362\u3002\u7b2c\u4e8c\u4e2a\u53cd\u5e94\uff08\u53f3\u5411\u5de6\uff09\u7684\u6b65\u4e3a\u70ef\u70c3\u7684\u787c\u6c22\u5316\u3002<\/p>\n

3.\u91d1\u5c5e\u8f6c\u79fb\uff08Transmetalation\uff09\u3002\u5728\u5178\u578b\u7684\u91d1\u5c5e\u8f6c\u79fb\u53cd\u5e94\u4e2d\uff0c\u4e8c\u82ef\u57fa\u6c5e\u548c\u950c\u5355\u8d28\u5728\u4e59\u919a\u4e2d\u53cd\u5e94\u5f97\u5230\u4e8c\u82ef\u57fa\u950c\u548c\u91d1\u5c5e\u6c5e\uff0c\u8be5\u53cd\u5e94\u901f\u7387\u5f88\u6162\u9700\u8981\u82b1\u8d39\u4e24\u5468\u65f6\u95f4\u3002<\/p>\n

4.\u6709\u673a\u950c\u5316\u5408\u7269\u8fd8\u53ef\u901a\u8fc7\u91d1\u5c5e\u950c\u76f4\u63a5\u83b7\u5f97\u3002\u8be5\u6cd5\u4e2d\uff0c\u950c\u901a\u8fc71,2-\u4e8c\u6eb4\u4e59\u70f7\u548c\u4e09\u7532\u57fa\u6c2f\u7845\u70f7\u6d3b\u5316\uff08\u5236\u5907\u683c\u6c0f\u8bd5\u5242\u4e5f\u53ef\u7528\u6b64\u6cd5\u8fdb\u884c\u6d3b\u5316\uff09\u3002\u5176\u4e2d\u7684\u5173\u952e\u8bd5\u5242\u4e3a\u6c2f\u5316\u9502\uff0c\u5b83\u80fd\u548c\u6709\u673a\u950c\u5316\u5408\u7269\u5feb\u901f\u7684\u5f62\u6210\u53ef\u6eb6\u52a0\u5408\u7269\u4ece\u800c\u5c06\u950c\u8bd5\u5242\u8131\u79bb\u91d1\u5c5e\u8868\u9762\u3002<\/p>\n

<\/p>\n

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\u6709\u673a\u950c\u5316\u5408\u7269\u5e38\u89c1\u7684\u6c27\u5316\u6001\u4e3a+2\u4ef7\u3002\u5b83\u53ef\u4ee5\u88ab\u5206\u4e3a\u4e09\u79cd\u7c7b\u578b\uff1a\u6709\u673a\u950c\u5364\u5316\u5408\u7269\uff08R-Zn-X\uff0c\u5176\u4e2dX\u4ee3\u8868\u5364\u7d20\u539f\u5b50\uff09\uff1b\u4e8c\u70c3\u57fa\u950c\u5316\u5408\u7269\uff08R-Zn-R\uff0c\u5176\u4e2dR\u4ee3\u8868\u70f7\u57fa\u6216\u82b3\u57fa\uff09\uff1b\u950c\u9178\u9502\u76d0\u6216\u950c\u9178\u9541\u76d0\uff08M+R3Zn-\uff0c\u5176\u4e2dM\u4ee3\u8868\u9502\u6216\u9541\uff09\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

\u6709\u673a\u950c \u4e0b\u5217\u4e3a\u4e00\u4e9b\u5408\u6210\u6709\u673a\u950c\u5316\u5408\u7269\u7684\u65b9\u6cd5\uff1a 1.\u6c27\u5316\u52a0\u6210\u3002\u65e9\u7531Frankland\u53d1\u73b0\u7684\u4e8c\u4e59\u57fa\u950c\u5373\u662f\u7528\u8be5\u6cd5\u5236\u5907\uff1a\u5728\u6c22\u6c14\u7684\u201c\u4fdd\u62a4\u201d\u4e0b\uff0c\u5c06\u7898\u4e59\u70f7\u548c… <\/p>\n","protected":false},"author":2,"featured_media":2365,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[3],"tags":[],"class_list":["post-2364","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-news"],"_links":{"self":[{"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/posts\/2364"}],"collection":[{"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/comments?post=2364"}],"version-history":[{"count":1,"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/posts\/2364\/revisions"}],"predecessor-version":[{"id":2368,"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/posts\/2364\/revisions\/2368"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/media\/2365"}],"wp:attachment":[{"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/media?parent=2364"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/categories?post=2364"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/tags?post=2364"}],"curies":[{"name":"wp","href":"http:\/\/api.w.org\/{rel}","templated":true}]}}