{"id":2238,"date":"2024-07-22T15:03:39","date_gmt":"2024-07-22T07:03:39","guid":{"rendered":"http:\/\/www.bdmaee.cn\/?p=2238"},"modified":"2024-07-22T16:00:54","modified_gmt":"2024-07-22T08:00:54","slug":"stille%e5%81%b6%e8%81%94%e5%8f%8d%e5%ba%94","status":"publish","type":"post","link":"http:\/\/www.bdmaee.cn\/archives\/2238","title":{"rendered":"Stille\u5076\u8054\u53cd\u5e94"},"content":{"rendered":"

Stille\u5076\u8054\u53cd\u5e94<\/strong><\/a><\/p>\n

Stille\u5076\u8054\u53cd\u5e94\u662f\u6307\u6709\u673a\u9521\u8bd5\u5242\u548c\u5364\u4ee3\u7269\u6216\u7c7b\u5364\u4ee3\u7269\u5728\u94af\u50ac\u5316\u4e0b\u8fdb\u884cCC\u952e\u5076\u8054\u7684\u53cd\u5e94\u3002\u6b64\u53cd\u5e94\u5bf9\u5364\u4ee3\u7269\u7684R\u57fa\u56e2\u9650\u5236\u8f83\u5c11\u3002\u53cd\u5e94\u7684\u6761\u4ef6\u6bd4\u8f83\u591a\uff0c\u53e6\u5916\u6b63\u5982\u4e0b\u65b9\u4ecb\u7ecd\u7684\u5364\u4ee3\u7269\u548c\u6709\u673a\u9521\u8bd5\u5242\u79cd\u7c7b\u5f88\u591a\uff0c\u4e92\u76f8\u8fdb\u884c\u5076\u8054\uff0c\u56e0\u6b64\u6b64\u53cd\u5e94\u53ef\u4ee5\u5408\u6210\u7684\u4ea7\u7269\u4e5f\u5f88\u591a\u3002\u672c\u53cd\u5e94\u7684\u7f3a\u70b9\u5c31\u662f\uff0c\u6709\u673a\u9521\u8bd5\u5242\u6bd2\u6027\u8f83\u5927\uff0c\u800c\u4e14\u5176\u6781\u6027\u8f83\u5c0f\uff0c\u5728\u6c34\u4e2d\u7684\u6eb6\u89e3\u5ea6\u5f88\u4f4e\u3002\u867d\u7136\u6709\u673a\u9521\u8bd5\u5242\u5f88\u7a33\u5b9a\uff0c\u4f46\u662f\u7531\u4e8e\u4e0eStille\u5076\u8054\u51e0\u4e4e\u76f8\u540c\u7684Suzuki \u53cd\u5e94\u7684\u53d1\u73b0\uff0cSuzuki \u53cd\u5e94\u4f7f\u7528\u6709\u673a\u787c\u9178\u53ca\u5176\u884d\u751f\u7269\uff0c\u4f7f\u7528\u65b9\u4fbf\u5e76\u4e14\u6ca1\u6709\u6709\u673a\u9521\u8bd5\u5242\u7684\u90a3\u4e9b\u7f3a\u70b9\uff0c\u56e0\u6b64\u6b64\u53cd\u5e94\u7684\u91cd\u8981\u6027\u8fc5\u901f\u964d\u4f4e\u3002<\/p>\n

<\/p>\n

Stille-Kelly\u53cd\u5e94<\/p>\n

\u94af\u50ac\u5316\u4e0b\u5206\u5b50\u5185\u7684\u4e8c\u82b3\u57fa\u5364\u4ee3\u7269\u5229\u7528\u4e8c\u9521\u8bd5\u5242\u8fdb\u884c\u4ea4\u53c9\u5076\u8054\u7684\u53cd\u5e94\u3002<\/p>\n

Stille\u7fb0\u57fa\u5316\u5076\u8054\u53cd\u5e94<\/p>\n

\u6b64\u53cd\u5e94\u7531Migita\u548cStille\u5f00\u53d1\uff0c\u5229\u7528\u9170\u6c2f\u8fdb\u884cStille\u5076\u8054\u53cd\u5e94\u5236\u5907\u916e\u3002\u4f46\u662f\u9170\u6c2f\u901a\u5e38\u4e0d\u7a33\u5b9a\u800c\u4e14\u5bf9\u4e8e\u6d3b\u6027\u5b98\u80fd\u56e2\u4e0d\u517c\u5bb9\uff0c\u9650\u5236\u4e86\u5176\u5e94\u7528\u8303\u56f4\u3002\u5728\u4e0a\u4e16\u7eaa80\u5e74\u4ee3\uff0c\u5728\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u4e0b\u6709\u673a\u5364\u4ee3\u70c3\u548c\u7c7b\u5364\u4ee3\u70c3\u8fdb\u884c\u7fb0\u57fa\u5316\u5076\u8054\u53cd\u5e94\u5236\u5907\u916e\u7684\u65b9\u6cd5\u88ab\u5f00\u53d1\u51fa\u6765\u3002Pd(0)\u50ac\u5316\u4e0b\uff0c\u6709\u673a\u9521\u8bd5\u5242\uff0c\u4e00\u6c27\u5316\u78b3\u548c\u6709\u673a\u4eb2\u7535\u8bd5\u5242\uff08\u82b3\u57fa\u6216\u70ef\u57fa\u5364\u4ee3\u70c3\u548c\u82b3\u57fa\u6216\u70ef\u57fa\u7c7b\u5364\u4ee3\u70c3\uff09\u5076\u8054\u5f62\u6210\u65b0\u7684\u78b3\u78b3\u5355\u952e\u7684\u53cd\u5e94\uff0c\u88ab\u79f0\u4e3aStille\u7fb0\u57fa\u5316\u5076\u8054\u53cd\u5e94\u3002<\/p>\n

<\/p>\n

Tsuji-Trost\u53cd\u5e94<\/p>\n

\u94af\u50ac\u5316\u4e0b\u5229\u7528\u70ef\u4e19\u57fa\u5316\u5408\u7269\uff08\u5982\u4e59\u9178\u70ef\u4e19\u916f\u548c\u70ef\u4e19\u57fa\u6eb4\uff09\u5bf9\u4eb2\u6838\u8bd5\u5242\uff08\u5982\u6d3b\u6027\u4e9a\u7532\u57fa\u5316\u5408\u7269\uff0c\u70ef\u9187\u5316\u5408\u7269\uff0c\u80fa\u548c\u915a\uff09\u8fdb\u884c\u70ef\u4e19\u57fa\u5316\u7684\u53cd\u5e94\u3002<\/p>\n

Catellani\u53cd\u5e94<\/p>\n

\u3010Catellani, M.; Frignani, F.; Rangoni, A. Angew. Chem. Int. Ed. Engl. 1997, 36,119\u2013122.\u3011<\/p>\n

\u5728\u964d\u51b0\u7247\u70ef(Norbornene)\u4e0ePd\u5171\u540c\u50ac\u5316\u4f5c\u7528\u4e0b\uff0c\u82b3\u57fa\u7898\u5316\u7269\u5148\u548c\u964d\u51b0\u7247\u70ef\u8fdb\u884cHeck\u53cd\u5e94\uff0c\u63a5\u7740\u90bb\u4f4dC-H\u6d3b\u5316\u8fdb\u884c\u70f7\u57fa\u5316\u6216\u82b3\u57fa\u5316\u7684\u53cd\u5e94\uff0c\u518d\u548c\u7aef\u57fa\u70ef\u70c3\u5076\u8054\u5f97\u5230\u90bb\u4f4d\u53d6\u4ee3\u7684\u70ef\u57fa\u82b3\u70c3\u7684\u53cd\u5e94\u3002\u6b64\u53cd\u5e94\u662f\u4e09\u7ec4\u5206\u5076\u8054\u53cd\u5e94\u3002\u90bb\u4f4d\u5355\u53d6\u4ee3\u7684\u82b3\u57fa\u7898\u5316\u7269\u4f5c\u4e3a\u5e95\u7269\u5219\u53ef\u4ee5\u5f97\u5230\u4e0d\u540c\u90bb\u4f4d\u53d6\u4ee3\u57fa\u7684\u70ef\u57fa\u82b3\u70c3\u3002<\/p>\n

<\/p>\n

White\u50ac\u5316\u5242<\/p>\n

White\u50ac\u5316\u5242\u662f\u4e00\u79cd\u591a\u7528\u9014\u7684\u5546\u4e1a\u5316\u50ac\u5316\u5242\u3002\u5728\u5176\u50ac\u5316\u4e0b\u53ef\u4ee5\u9ad8\u6548\u5730\u6c27\u5316\u76f8\u5bf9\u60f0\u6027\u7684C-H\u952e\u5f62\u6210\u65b0\u7684C-O, C-N\u548cC-C\u952e\u3002\u5404\u79cd\u70ef\u70c3\u90fd\u53ef\u4ee5\u8fdb\u884c\u5206\u5b50\u5185\u6216\u5206\u5b50\u95f4\u7684C-H\u6c27\u5316\uff0c\u5e76\u5177\u6709\u5f88\u9ad8\u7684\u5316\u5b66\uff0c\u533a\u57df\u548c\u7acb\u4f53\u9009\u62e9\u6027\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"

Stille\u5076\u8054\u53cd\u5e94 Stille\u5076\u8054\u53cd\u5e94\u662f\u6307\u6709\u673a\u9521\u8bd5\u5242\u548c\u5364\u4ee3\u7269\u6216\u7c7b\u5364\u4ee3\u7269\u5728\u94af\u50ac\u5316\u4e0b\u8fdb\u884cCC\u952e\u5076\u8054\u7684\u53cd\u5e94\u3002\u6b64\u53cd\u5e94\u5bf9\u5364\u4ee3\u7269\u7684R\u57fa\u56e2\u9650\u5236\u8f83\u5c11\u3002\u53cd… <\/p>\n","protected":false},"author":2,"featured_media":2239,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[3],"tags":[],"class_list":["post-2238","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-news"],"_links":{"self":[{"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/posts\/2238"}],"collection":[{"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/comments?post=2238"}],"version-history":[{"count":2,"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/posts\/2238\/revisions"}],"predecessor-version":[{"id":2249,"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/posts\/2238\/revisions\/2249"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/media\/2239"}],"wp:attachment":[{"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/media?parent=2238"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/categories?post=2238"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/tags?post=2238"}],"curies":[{"name":"wp","href":"http:\/\/api.w.org\/{rel}","templated":true}]}}