\u5206\u5b50\u7b5b\u7684\u6982\u5ff5<\/strong><\/a><\/p>\n\u5206\u5b50\u7b5b\u662f\u7ed3\u6676\u578b\u7684\u7845\u94dd\u9178\u76d0\uff0c\u5177\u6709\u5747\u5300\u7684\u5b54\u9699\u7ed3\u6784\u3002\u5206\u5b50\u7b5b\u4e2d\u542b\u6709\u5927\u91cf\u7684\u7ed3\u6676\u6c34\uff0c\u52a0\u70ed\u65f6\u53ef\u6c7d\u5316\u9664\u53bb\uff0c\u6545\u53c8\u79f0\u6cb8\u77f3\u3002\u81ea\u7136\u754c\u5b58\u5728\u7684\u5e38\u79f0\u6cb8\u77f3\uff0c\u4eba\u5de5\u5408\u6210\u7684\u79f0\u4e3a\u5206\u5b50\u7b5b\u3002\u5b83\u4eec\u7684\u5316\u5b66\u7ec4\u6210\u53ef\u8868\u793a\u4e3a<\/p>\n
Mx\/n[(AlO2)x(SiO2)y] ZH2O<\/p>\n
\u5f0f\u4e2dM\u662f\u91d1\u5c5e\u9633\u79bb\u5b50\uff0cn\u662f\u5b83\u7684\u4ef7\u6570\uff0cx\u662fAlO2\u7684\u5206\u5b50\u6570\uff0cy\u662fSiO2\u5206\u5b50\u6570\uff0cZ\u662f\u6c34\u5206\u5b50\u6570\uff0c\u56e0\u4e3aAlO2\u5e26\u8d1f\u7535\u8377\uff0c\u91d1\u5c5e\u9633\u79bb\u5b50\u7684\u5b58\u5728\u53ef\u4f7f\u5206\u5b50\u7b5b\u4fdd\u6301\u7535\u4e2d\u6027\u3002\u5f53\u91d1\u5c5e\u79bb\u5b50\u7684\u5316\u5408\u4ef7n = 1\u65f6\uff0cM\u7684\u539f\u5b50\u6570\u7b49\u4e8eAl\u7684\u539f\u5b50\u6570\uff1b\u82e5n = 2\uff0cM\u7684\u539f\u5b50\u6570\u4e3aAl\u539f\u5b50\u6570\u7684\u4e00\u534a\u3002<\/p>\n
\u5e38\u7528\u7684\u5206\u5b50\u7b5b\u4e3b\u8981\u6709\uff1a\u65b9\u94a0\u578b\u6cb8\u77f3\uff0c\u5982A\u578b\u5206\u5b50\u7b5b\uff1b\u516b\u9762\u578b\u6cb8\u77f3\uff0c\u5982X-\u578b\uff0cY-\u578b\u5206\u5b50\u7b5b\uff1b\u4e1d\u5149\u578b\u6cb8\u77f3\uff08-M\u578b\uff09\uff1b\u9ad8\u7845\u578b\u6cb8\u77f3\uff0c\u5982ZSM-5\u7b49\u3002\u5206\u5b50\u7b5b\u5728\u5404\u79cd\u4e0d\u540c\u7684\u9178\u6027\u50ac\u5316\u5242\u4e2d\u80fd\u591f\u63d0\u4f9b\u5f88\u9ad8\u7684\u6d3b\u6027\u548c\u4e0d\u5bfb\u5e38\u7684\u9009\u62e9\u6027\uff0c\u4e14\u7edd\u5927\u591a\u6570\u53cd\u5e94\u662f\u7531\u5206\u5b50\u7b5b\u7684\u9178\u6027\u5f15\u8d77\u7684\uff0c\u4e5f\u5c5e\u4e8e\u56fa\u4f53\u9178\u7c7b\u3002\u8fd120\u5e74\u6765\u5728\u5de5\u4e1a\u4e0a\u5f97\u5230\u4e86\u5e7f\u6cdb\u5e94\u7528\uff0c\u5c24\u5176\u5728\u70bc\u6cb9\u5de5\u4e1a\u548c\u77f3\u6cb9\u5316\u5de5\u4e2d\u4f5c\u4e3a\u5de5\u4e1a\u50ac\u5316\u5242\u5360\u6709\u91cd\u8981\u5730\u4f4d\u3002<\/p>\n
<\/p>\n
2.\u5206\u5b50\u7b5b\u7684\u7ed3\u6784\u7279\u5f81 \uff081\uff09\u56db\u4e2a\u65b9\u9762\u3001\u4e09\u79cd\u5c42\u6b21\uff1a<\/p>\n
\u5206\u5b50\u7b5b\u7684\u7ed3\u6784\u7279\u5f81\u53ef\u4ee5\u5206\u4e3a\u56db\u4e2a\u65b9\u9762\u3001\u4e09\u79cd\u4e0d\u540c\u7684\u7ed3\u6784\u5c42\u6b21\u3002\u4e2a\u7ed3\u6784\u5c42\u6b21\u4e5f\u5c31\u662f\u57fa\u672c\u7684\u7ed3\u6784\u5355\u5143\u7845\u6c27\u56db\u9762\u4f53\uff08SiO4\uff09\u548c\u94dd\u6c27\u56db\u9762\u4f53\uff08AlO4\uff09\uff0c\u5b83\u4eec\u6784\u6210\u5206\u5b50\u7b5b\u7684\u9aa8\u67b6\u3002\u76f8\u90bb\u7684\u56db\u9762\u4f53\u7531\u6c27\u6865\u8fde\u7ed3\u6210\u73af\u3002\u73af\u662f\u5206\u5b50\u7b5b\u7ed3\u6784\u7684\u7b2c\u4e8c\u4e2a\u5c42\u6b21\uff0c\u6309\u6210\u73af\u7684\u6c27\u539f\u5b50\u6570\u5212\u5206\uff0c\u6709\u56db\u5143\u6c27\u73af\u3001\u4e94\u5143\u6c27\u73af\u3001\u516d\u5143\u6c27\u73af\u3001\u516b\u5143\u6c27\u73af\u3001\u5341\u5143\u6c27\u73af\u548c\u5341\u4e8c\u5143\u6c27\u73af\u7b49\u3002\u73af\u662f\u5206\u5b50\u7b5b\u7684\u901a\u9053\u5b54\u53e3\uff0c\u5bf9\u901a\u8fc7\u5206\u5b50\u8d77\u7740\u7b5b\u5206\u4f5c\u7528\u3002\u6c27\u73af\u901a\u8fc7\u6c27\u6865\u76f8\u4e92\u8054\u7ed3\uff0c\u5f62\u6210\u5177\u6709\u4e09\u7ef4\u7a7a\u95f4\u7684\u591a\u9762\u4f53\u3002\u5404\u79cd\u5404\u6837\u7684\u591a\u9762\u4f53\u662f\u5206\u5b50\u7b5b\u7ed3\u6784\u7684\u7b2c\u4e09\u4e2a\u5c42\u6b21\u3002\u591a\u9762\u4f53\u6709\u4e2d\u7a7a\u7684\u7b3c\uff0c\u7b3c\u662f\u5206\u5b50\u7b5b\u7ed3\u6784\u7684\u91cd\u8981\u7279\u5f81\u3002\u7b3c\u5206\u4e3a\u03b1\u7b3c\uff0c\u516b\u9762\u6cb8\u77f3\u7b3c\uff0c\u03b2\u7b3c\u548c\u03b3\u7b3c\u7b49\u3002<\/p>\n
\uff082\uff09\u5206\u5b50\u7b5b\u7684\u7b3c\uff1a<\/p>\n
\u03b1\u7b3c\uff1a\u662fA\u578b\u5206\u5b50\u7b5b\u9aa8\u67b6\u7ed3\u6784\u7684\u4e3b\u8981\u5b54\u7a74\uff0c\u5b83\u662f\u753112\u4e2a\u56db\u5143\u73af\uff0c8\u4e2a\u516d\u5143\u73af\u53ca6\u4e2a\u516b\u5143\u73af\u7ec4\u6210\u7684\u4e8c\u5341\u516d\u9762\u4f53\u3002\u7b3c\u7684\u5e73\u5747\u5b54\u5f84\u4e3a1.14nm\uff0c\u7a7a\u8154\u4f53\u79ef\u4e3a760[]3\u3002\u03b1\u7b3c\u7684\u5927\u7a97\u5b54\u4e3a\u516b\u5143\u73af\uff0c\u5b54\u5f840.41nm\u3002<\/p>\n
\u516b\u9762\u6cb8\u77f3\u7b3c\uff1a\u662f\u6784\u6210X-\u578b\u548cY-\u578b\u5206\u5b50\u7b5b\u9aa8\u67b6\u7684\u4e3b\u8981\u5b54\u7a74\uff0c\u753118\u4e2a\u56db\u5143\u73af\u30014\u4e2a\u516d\u5143\u73af\u548c4\u4e2a\u5341\u4e8c\u5143\u73af\u7ec4\u6210\u7684\u4e8c\u5341\u516d\u9762\u4f53\uff0c\u7b3c\u7684\u5e73\u5747\u5b54\u5f84\u4e3a1.25nm\uff0c\u7a7a\u8154\u4f53\u79ef\u4e3a850[]3\u3002\u5927\u5b54\u7a97\u4e3a\u5341\u4e8c\u5143\u73af\uff0c\u5b54\u5f840.74nm\u3002\u516b\u9762\u6cb8\u77f3\u7b3c\u4e5f\u79f0\u8d85\u7b3c\u3002<\/p>\n
\u03b2\u7b3c\uff1a\u4e3b\u8981\u7528\u4e8e\u6784\u6210A\u578b\u3001X-\u578b\u548cY\u578b\u5206\u5b50\u7b5b\u7684\u9aa8\u67b6\u7ed3\u6784\uff0c\u662f\u91cd\u8981\u7684\u4e00\u79cd\u5b54\u7a74\uff0c\u5b83\u7684\u5f62\u72b6\u5b9b\u5982\u6709\u5173\u524a\u9876\u7684\u6b63\u516b\u9762\u4f53\uff0c\u7a7a\u8154\u4f53\u79ef\u4e3a160[]3\uff0c\u7a97\u53e3\u5b54\u5f84\u4e3a\u7ea60.66nm\uff0c\u53ea\u5141\u8bb8NH3\u3001H2O\u7b49\u5c3a\u5bf8\u8f83\u5c0f\u7684\u5206\u5b50\u8fdb\u5165\u3002<\/p>\n
\u6b64\u5916\u8fd8\u6709\u516d\u65b9\u67f1\u7b3c\u548c\u03b3\u7b3c\uff0c\u8fd9\u4e24\u79cd\u7b3c\u4f53\u79ef\u8f83\u5c0f\uff0c\u4e00\u822c\u5206\u5b50\u8fdb\u4e0d\u5230\u7b3c\u91cc\u53bb\u3002<\/p>\n
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\uff083\uff09\u51e0\u79cd\u5177\u6709\u4ee3\u8868\u6027\u7684\u5206\u5b50\u7b5b<\/p>\n
A\u578b\u5206\u5b50\u7b5b<\/p>\n
\u7c7b\u4f3c\u4e8eNaCl\u7684\u7acb\u65b9\u6676\u7cfb\u7ed3\u6784\u3002\u82e5\u5c06NaCl\u6676\u683c\u4e2d\u7684Na+\u548cCl-\u5168\u90e8\u6362\u6210\u03b2\u7b3c\uff0c\u5e76\u5c06\u76f8\u90bb\u7684\u03b2\u7b3c\u7528\u03b3\u7b3c\u8054\u7ed3\u8d77\u6765\u5c31\u5f97\u5230A-\u578b\u5206\u5b50\u7b5b\u7684\u6676\u4f53\u7ed3\u6784\u30028\u4e2a\u03b2\u7b3c\u8054\u7ed3\u540e\u5f62\u6210\u4e00\u4e2a\u65b9\u94a0\u77f3\u7ed3\u6784\uff0c\u5982\u7528\u03b3\u7b3c\u505a\u6865\u8054\u7ed3\uff0c\u5c31\u5f97\u5230A-\u578b\u5206\u5b50\u7b5b\u7ed3\u6784\u3002\u4e2d\u5fc3\u6709\u4e00\u4e2a\u5927\u7684\u03b1\u7684\u7b3c\u3002\u03b1\u7b3c\u4e4b\u95f4\u901a\u9053\u6709\u4e00\u4e2a\u516b\u5143\u73af\u7a97\u53e3\uff0c\u5176\u76f4\u5f84\u4e3a4\uff0c\u6545\u79f04A\u5206\u5b50\u7b5b\u3002\u82e54A\u5206\u5b50\u7b5b\u4e0a70%\u7684Na+\u4e3aCa2+\u4ea4\u6362\uff0c\u516b\u5143\u73af\u53ef\u589e\u81f35\uff0c\u5bf9\u5e94\u7684\u6cb8\u77f3\u79f05A\u5206\u5b50\u7b5b\u3002\u53cd\u4e4b\uff0c\u82e570%\u7684Na+\u4e3aK+\u4ea4\u6362\uff0c\u516b\u5143\u73af\u5b54\u5f84\u7f29\u5c0f\u52303\uff0c\u5bf9\u5e94\u7684\u6cb8\u77f3\u79f03A\u5206\u5b50\u7b5b\u3002<\/p>\n
X-\u578b\u548cY-\u578b\u5206\u5b50\u7b5b<\/p>\n
\u7c7b\u4f3c\u91d1\u521a\u77f3\u7684\u5bc6\u5806\u516d\u65b9\u6676\u7cfb\u7ed3\u6784\u3002\u82e5\u4ee5\u03b2\u7b3c\u4e3a\u7ed3\u6784\u5355\u5143\uff0c\u53d6\u4ee3\u91d1\u521a\u77f3\u7684\u78b3\u539f\u5b50\u7ed3\u70b9\uff0c\u4e14\u7528\u516d\u65b9\u67f1\u7b3c\u5c06\u76f8\u90bb\u7684\u4e24\u4e2a\u03b2\u7b3c\u8054\u7ed3\uff0c\u5373\u75284\u4e2a\u516d\u65b9\u67f1\u7b3c\u5c065\u4e2a\u03b2\u7b3c\u8054\u7ed3\u4e00\u8d77\uff0c\u5176\u4e2d\u4e00\u4e2a\u03b2\u7b3c\u5c45\u4e2d\u5fc3\uff0c\u5176\u4f594\u4e2a\u03b2\u7b3c\u4f4d\u4e8e\u6b63\u56db\u9762\u4f53\u9876\u70b9\uff0c\u5c31\u5f62\u6210\u4e86\u516b\u9762\u4f53\u6cb8\u77f3\u578b\u7684\u6676\u4f53\u7ed3\u6784\u3002\u7528\u8fd9\u79cd\u7ed3\u6784\u7ee7\u7eed\u8fde\u7ed3\u4e0b\u53bb\uff0c\u5c31\u5f97\u5230X-\u578b\u548cY\u578b\u5206\u5b50\u7b5b\u7ed3\u6784\u3002\u5728\u8fd9\u79cd\u7ed3\u6784\u4e2d\uff0c\u7531\u03b2\u7b3c\u548c\u516d\u65b9\u67f1\u7b3c\u5f62\u6210\u7684\u5927\u7b3c\u4e3a\u516b\u9762\u6cb8\u77f3\u7b3c\uff0c\u5b83\u4eec\u76f8\u901a\u7684\u7a97\u5b54\u4e3a\u5341\u4e8c\u5143\u73af\uff0c\u5176\u5e73\u5747\u6709\u6548\u5b54\u5f84\u4e3a0.74nm\uff0c\u8fd9\u5c31\u662fX-\u578b\u548cY-\u578b\u5206\u5b50\u7b5b\u7684\u5b54\u5f84\u3002\u8fd9\u4e24\u79cd\u578b\u53f7\u5f7c\u6b64\u95f4\u7684\u5dee\u5f02\u4e3b\u8981\u662fSi\/Al\u6bd4\u4e0d\u540c\uff0cX-\u578b\u4e3a1~1.5\uff1bY\u578b\u4e3a1.5~3.0\u3002<\/p>\n
\u4e1d\u5149\u6cb8\u77f3\u578b\u5206\u5b50\u7b5b<\/p>\n
\u8fd9\u79cd\u6cb8\u77f3\u7684\u7ed3\u6784\uff0c\u6ca1\u6709\u7b3c\u800c\u662f\u5c42\u72b6\u7ed3\u6784\u3002\u7ed3\u6784\u4e2d\u542b\u6709\u5927\u91cf\u7684\u4e94\u5143\u73af\uff0c\u4e14\u6210\u5bf9\u5730\u8054\u7cfb\u5728\u4e00\u8d77\uff0c\u6bcf\u5bf9\u4e94\u5143\u73af\u901a\u8fc7\u6c27\u6865\u518d\u4e0e\u53e6\u4e00\u5bf9\u8054\u7ed3\u3002\u8054\u7ed3\u5904\u5f62\u6210\u56db\u5143\u73af\u3002\u8fd9\u79cd\u7ed3\u6784\u5355\u5143\u8fdb\u4e00\u6b65\u8054\u7ed3\u5f62\u6210\u5c42\u72b6\u7ed3\u6784\u3002\u5c42\u4e2d\u6709\u516b\u5143\u73af\u548c\u5341\u4e8c\u5143\u73af\uff0c\u540e\u8005\u5448\u692d\u5706\u5f62\uff0c\u5e73\u5747\u76f4\u5f840.74nm\uff0c\u662f\u4e1d\u5149\u6cb8\u77f3\u7684\u4e3b\u5b54\u9053\u3002\u8fd9\u79cd\u5b54\u9053\u662f\u4e00\u7ef4\u7684\uff0c\u5373\u76f4\u901a\u9053\u3002<\/p>\n
\u9ad8\u7845\u6cb8\u77f3ZSM\uff08Zeolite Socony Mobil\uff09\u578b\u5206\u5b50\u7b5b<\/p>\n
\u8fd9\u79cd\u6cb8\u77f3\u6709\u4e00\u4e2a\u7cfb\u5217\uff0c\u5e7f\u6cdb\u5e94\u7528\u7684\u4e3aZSM-5\uff0c\u4e0e\u4e4b\u7ed3\u6784\u76f8\u540c\u7684\u6709ZSM-8\u548cZSM-11\uff1b\u53e6\u4e00\u7ec4\u4e3aZSM-21\u3001ZSM-35\u548cZSM-38\u7b49\u3002ZSM-5\u5e38\u79f0\u4e3a\u9ad8\u7845\u578b\u6cb8\u77f3\uff0c\u5176Si\/Al\u6bd4\u53ef\u9ad8\u8fbe50\u4ee5\u4e0a\uff0cZSM-8\u53ef\u9ad8\u8fbe100\uff0c\u8fd9\u7ec4\u5206\u5b50\u7b5b\u8fd8\u663e\u51fa\u618e\u6c34\u7684\u7279\u6027\u3002\u5b83\u4eec\u7684\u7ed3\u6784\u5355\u5143\u4e0e\u4e1d\u5149\u6cb8\u77f3\u76f8\u4f3c\uff0c\u7531\u6210\u5bf9\u7684\u4e94\u5143\u73af\u7ec4\u6210\uff0c\u65e0\u7b3c\u72b6\u7a7a\u8154\uff0c\u53ea\u6709\u901a\u9053\u3002ZSM-5\u6709\u4e24\u7ec4\u4ea4\u53c9\u7684\u901a\u9053\uff0c\u4e00\u79cd\u4e3a\u76f4\u901a\u7684\uff0c\u53e6\u4e00\u79cd\u4e3a\u4e4b\u5b57\u578b\u76f8\u4e92\u5782\u76f4\uff0c\u90fd\u7531\u5341\u5143\u73af\u5f62\u6210\u3002\u901a\u9053\u5448\u692d\u5706\u5f62\uff0c\u5176\u7a97\u53e3\u76f4\u5f84\u4e3a\uff080.55-0.60\uff09nm\u3002\u5c5e\u4e8e\u9ad8\u7845\u65cf\u7684\u6cb8\u77f3\u8fd8\u6709\u5168\u7845\u578b\u7684Silicalite-1\uff0c\u7ed3\u6784\u4e0eZSM-5\u4e00\u6837\uff0cSilicalite-2\u4e0eZSM-11\u4e00\u6837\u3002<\/p>\n
\u78f7\u9178\u94dd\u7cfb\u5206\u5b50\u7b5b<\/p>\n
\u8be5\u7cfb\u6cb8\u77f3\u662f\u7ee760\u5e74\u4ee3Y-\u578b\u5206\u5b50\u7b5b\uff0c70\u5e74\u4ee3ZSM-5\u578b\u9ad8\u7845\u5206\u5b50\u7b5b\u4e4b\u540e\uff0c\u4e8e80\u5e74\u4ee3\u51fa\u73b0\u7684\u7b2c\u4e09\u4ee3\u65b0\u578b\u5206\u5b50\u7b5b\u3002\u5305\u62ec\u5927\u5b54\u7684AlPO-5\uff080.1-0.8nm\uff09\uff0c\u4e2d\u5b54\u7684AlPO-11\uff080.6nm\uff09\u548c\u5c0f\u5b54\u7684AlPO-34\uff080.4nm\uff09\u7b49\u7ed3\u6784\u53caMAPO-n\u7cfb\u5217\u548cAlPO\u5f84\u7ecfSi\u5316\u5b66\u6539\u6027\u6210\u7684SAPO\u7cfb\u5217\u7b49\u3002<\/p>\n
4\u3001\u5206\u5b50\u7b5b\u50ac\u5316\u5242\u7684\u50ac\u5316\u4f5c\u7528\u673a\u7406<\/p>\n
\u5206\u5b50\u7b5b\u5177\u6709\u660e\u786e\u7684\u5b54\u8154\u5206\u5e03\uff0c\u6781\u9ad8\u7684\u5185\u8868\u9762\u79ef\uff08600m2\/s\uff09\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\uff081000\u2103\uff09\uff0c\u53ef\u8c03\u53d8\u7684\u9178\u4f4d\u4e2d\u5fc3\u3002\u5206\u5b50\u7b5b\u9178\u6027\u4e3b\u8981\u6765\u6e90\u4e8e\u9aa8\u67b6\u4e0a\u548c\u5b54\u9699\u4e2d\u7684\u4e09\u914d\u4f4d\u7684\u94dd\u539f\u5b50\u548c\u94dd\u79bb\u5b50(AlO)+\u3002\u7ecf\u79bb\u5b50\u4ea4\u6362\u5f97\u5230\u7684\u5206\u5b50\u7b5bHY\u4e0a\u7684OH\u57fa\u663e\u9178\u4f4d\u4e2d\u5fc3\uff0c\u9aa8\u67b6\u5916\u7684\u94dd\u79bb\u5b50\u4f1a\u5f3a\u5316\u9178\u4f4d\uff0c\u5f62\u6210L\u9178\u4f4d\u4e2d\u5fc3\u3002\u50cfCa2+\u3001Mg2+\u3001La3+\u7b49\u591a\u4ef7\u9633\u79bb\u5b50\u7ecf\u4ea4\u6362\u540e\u53ef\u4ee5\u663e\u793a\u9178\u4f4d\u4e2d\u5fc3\u3002Cu2+\u3001Ag+\u7b49\u8fc7\u6e21\u91d1\u5c5e\u79bb\u5b50\u8fd8\u539f\u4e5f\u80fd\u5f62\u6210\u9178\u4f4d\u4e2d\u5fc3\u3002\u4e00\u822c\u6765\u8bf4Al\/Si\u6bd4\u8d8a\u9ad8\uff0cOH\u57fa\u7684\u6bd4\u6d3b\u6027\u8d8a\u9ad8\u3002\u5206\u5b50\u7b5b\u9178\u6027\u7684\u8c03\u53d8\u53ef\u901a\u8fc7\u7a00\u76d0\u9178\u76f4\u63a5\u4ea4\u6362\u5c06\u8d28\u5b50\u5f15\u5165\u3002\u7531\u4e8e\u8fd9\u79cd\u529e\u6cd5\u5e38\u5bfc\u81f4\u5206\u5b50\u7b5b\u9aa8\u67b6\u8131\u94dd\u3002\u6240\u4ee5NaY\u8981\u53d8\u6210NH4Y\uff0c\u7136\u540e\u518d\u53d8\u4e3aHY\u3002<\/p>\n
\uff081\uff09\u5206\u5b50\u7b5b\u5177\u62e9\u5f62\u50ac\u5316\u7684\u6027\u8d28<\/p>\n
\u56e0\u4e3a\u5206\u5b50\u7b5b\u7ed3\u6784\u4e2d\u6709\u5747\u5300\u7684\u5c0f\u5185\u5b54\uff0c\u5f53\u53cd\u5e94\u7269\u548c\u4ea7\u7269\u7684\u5206\u5b50\u7ebf\u5ea6\u4e0e\u6676\u5185\u7684\u5b54\u5f84\u76f8\u63a5\u8fd1\u65f6\uff0c\u50ac\u5316\u53cd\u5e94\u7684\u9009\u62e9\u6027\u5e38\u53d6\u51b3\u4e8e\u5206\u5b50\u4e0e\u5b54\u5f84\u7684\u76f8\u5e94\u5927\u5c0f\u3002\u8fd9\u79cd\u9009\u62e9\u6027\u79f0\u4e4b\u4e3a\u62e9\u5f62\u50ac\u5316\u3002\u5bfc\u81f4\u62e9\u5f62\u9009\u62e9\u6027\u7684\u673a\u7406\u6709\u4e24\u79cd\uff0c\u4e00\u79cd\u662f\u7531\u5b54\u8154\u4e2d\u53c2\u4e0e\u53cd\u5e94\u7684\u5206\u5b50\u7684\u6269\u6563\u7cfb\u6570\u5dee\u522b\u5f15\u8d77\u7684\uff0c\u79f0\u4e3a\u8d28\u91cf\u4f20\u9012\u9009\u62e9\u6027\uff1b\u53e6\u4e00\u79cd\u662f\u7531\u50ac\u5316\u53cd\u5e94\u8fc7\u6e21\u6001\u7a7a\u95f4\u9650\u5236\u5f15\u8d77\u7684\uff0c\u79f0\u4e3a\u8fc7\u6e21\u6001\u9009\u62e9\u6027\u3002\u62e9\u5f62\u50ac\u5316\u67094\u79cd\u5f62\u5f0f\uff1a<\/p>\n
<\/p>\n
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\u5f53\u53cd\u5e94\u6df7\u5408\u7269\u4e2d\u67d0\u4e9b\u80fd\u53cd\u5e94\u7684\u5206\u5b50\u56e0\u592a\u5927\u800c\u4e0d\u80fd\u6269\u6563\u8fdb\u5165\u50ac\u5316\u5242\u5b54\u8154\u5185\uff0c\u53ea\u6709\u90a3\u4e9b\u76f4\u5f84\u5c0f\u4e8e\u5185\u5b54\u5f84\u7684\u5206\u5b50\u624d\u80fd\u8fdb\u5165\u5185\u5b54\uff0c\u5728\u50ac\u5316\u6d3b\u6027\u90e8\u5206\u8fdb\u884c\u53cd\u5e94\u3002<\/p>\n
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\u8fc7\u6e21\u6001\u9650\u5236\u7684\u9009\u62e9\u6027<\/p>\n
\u6709\u4e9b\u53cd\u5e94\uff0c\u5176\u53cd\u5e94\u7269\u5206\u5b50\u548c\u4ea7\u7269\u5206\u5b50\u90fd\u4e0d\u53d7\u50ac\u5316\u5242\u7a97\u53e3\u5b54\u5f84\u6269\u6563\u7684\u9650\u5236\uff0c\u53ea\u662f\u7531\u4e8e\u9700\u8981\u5185\u5b54\u6216\u7b3c\u8154\u6709\u8f83\u5927\u7684\u7a7a\u95f4\uff0c\u624d\u80fd\u5f62\u6210\u76f8\u5e94\u7684\u8fc7\u6e21\u6001\uff0c\u4e0d\u7136\u5c31\u53d7\u5230\u9650\u5236\u4f7f\u8be5\u53cd\u5e94\u65e0\u6cd5\u8fdb\u884c\uff1b\u76f8\u53cd\uff0c\u6709\u4e9b\u53cd\u5e94\u53ea\u9700\u8981\u8f83\u5c0f\u7a7a\u95f4\u7684\u8fc7\u6e21\u6001\u5c31\u4e0d\u53d7\u8fd9\u79cd\u9650\u5236\uff0c\u8fd9\u5c31\u6784\u6210\u4e86\u9650\u5236\u8fc7\u6e21\u6001\u7684\u62e9\u5f62\u50ac\u5316\u3002<\/p>\n
ZSM-5\u5e38\u7528\u4e8e\u8fd9\u79cd\u8fc7\u6e21\u6001\u9009\u62e9\u6027\u7684\u50ac\u5316\u53cd\u5e94\uff0c\u5927\u4f18\u70b9\u662f\u963b\u6b62\u7ed3\u7126\u3002\u56e0\u4e3aZSM-5\u8f83\u5176\u4ed6\u5206\u5b50\u7b5b\u5177\u6709\u8f83\u5c0f\u7684\u5185\u5b54\uff0c\u4e0d\u5229\u4e8e\u7126\u751f\u6210\u7684\u524d\u9a71\u7269\u805a\u5408\u53cd\u5e94\u9700\u8981\u7684\u5927\u7684\u8fc7\u6e21\u6001\u5f62\u6210\u3002\u56e0\u800c\u6bd4\u522b\u7684\u5206\u5b50\u7b5b\u548c\u65e0\u5b9a\u5f62\u50ac\u5316\u5242\u5177\u6709\u66f4\u957f\u7684\u5bff\u547d\u3002<\/p>\n
\u5206\u5b50\u4ea4\u901a\u63a7\u5236\u7684\u62e9\u5f62\u50ac\u5316<\/p>\n
\u5728\u5177\u6709\u4e24\u79cd\u4e0d\u540c\u5f62\u72b6\u548c\u5927\u5c0f\u548c\u5b54\u9053\u5206\u5b50\u7b5b\u4e2d\uff0c\u53cd\u5e94\u7269\u5206\u5b50\u53ef\u4ee5\u5f88\u5bb9\u6613\u5730\u901a\u8fc7\u4e00\u79cd\u5b54\u9053\u8fdb\u5165\u5230\u50ac\u5316\u5242\u7684\u6d3b\u6027\u90e8\u4f4d\uff0c\u8fdb\u884c\u50ac\u5316\u53cd\u5e94\uff0c\u800c\u4ea7\u7269\u5206\u5b50\u5219\u4ece\u53e6\u4e00\u5b54\u9053\u6269\u6563\u51fa\u53bb\uff0c\u5c3d\u53ef\u80fd\u5730\u51cf\u5c11\u9006\u6269\u6563\uff0c\u4ece\u9762\u589e\u52a0\u53cd\u5e94\u901f\u7387\u3002\u8fd9\u79cd\u5206\u5b50\u4ea4\u901a\u63a7\u5236\u7684\u50ac\u5316\u53cd\u5e94\uff0c\u662f\u4e00\u79cd\u7279\u6b8a\u5f62\u5f0f\u7684\u62e9\u5f62\u9009\u62e9\u6027\uff0c\u79f0\u5206\u5b50\u4ea4\u901a\u63a7\u5236\u62e9\u5f62\u50ac\u5316\u3002<\/p>\n
\uff082\uff09\u62e9\u5f62\u9009\u62e9\u6027\u7684\u8c03\u53d8<\/p>\n
\u53ef\u4ee5\u901a\u8fc7\u6bd2\u5316\u5916\u8868\u9762\u6d3b\u6027\u4e2d\u5fc3\uff1b\u4fee\u9970\u7a97\u5b54\u5165\u53e3\u7684\u5927\u5c0f\uff0c\u5e38\u7528\u7684\u4fee\u9970\u5242\u4e3a\u56db\u4e59\u57fa\u539f\u7845\u9178\u916f\uff1b\u4e5f\u53ef\u6539\u53d8\u6676\u7c92\u5927\u5c0f\u7b49\u3002<\/p>\n
\u62e9\u5f62\u50ac\u5316\u5927\u7684\u5b9e\u7528\u4ef7\u503c\uff0c\u5728\u4e8e\u5229\u7528\u5b83\u8868\u5f81\u5b54\u7ed3\u6784\u7684\u4e0d\u540c\uff0c\u662f\u533a\u522b\u9178\u6027\u5206\u5b50\u7b5b\u7684\u65b9\u6cd5\u4e4b\u4e00\u3002\u62e9\u5f62\u50ac\u5316\u5728\u70bc\u6cb9\u5de5\u827a\u548c\u77f3\u6cb9\u5de5\u4e1a\u751f\u4ea7\u4e2d\u53d6\u5f97\u4e86\u5e7f\u6cdb\u7684\u5e94\u7528\uff0c\u5982\u5206\u5b50\u7b5b\u8131\u814a\u3001\u62e9\u5f62\u5f02\u6784\u5316\u3001\u62e9\u5f62\u91cd\u6574\u3001\u7532\u9187\u5408\u6210\u6c7d\u6cb9\u3001\u7532\u9187\u5236\u4e59\u70ef\u3001\u82b3\u70c3\u62e9\u5f62\u70f7\u57fa\u5316\u7b49\u3002<\/p>\n
<\/p>\n
\u4e09\u3001\u91d1\u5c5e\u50ac\u5316\u5242\u53ca\u5176\u50ac\u5316\u5242\u4f5c\u7528\u673a\u7406<\/p>\n
1.\u91d1\u5c5e\u50ac\u5316\u5242\u6982\u8ff0<\/p>\n
\u91d1\u5c5e\u50ac\u5316\u5242\u662f\u4e00\u7c7b\u91cd\u8981\u7684\u5de5\u4e1a\u50ac\u5316\u5242\u3002\u4e3b\u8981\u5305\u62ec\u5757\u72b6\u50ac\u5316\u5242\uff0c\u5982\u7535\u89e3\u94f6\u50ac\u5316\u5242\u3001\u878d\u94c1\u50ac\u5316\u5242\u3001\u94c2\u7f51\u50ac\u5316\u5242\u7b49\uff1b\u5206\u6563\u6216\u8005\u8d1f\u8f7d\u578b\u7684\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u5982Pt-Re\/-Al2O3\u91cd\u6574\u50ac\u5316\u5242\uff0cNi\/Al2O3\u52a0\u6c22\u50ac\u5316\u5242\u7b49\uff1b<\/p>\n
6.3 \u91d1\u5c5e\u50ac\u5316\u5242\u53ca\u5176\u50ac\u5316\u5242\u4f5c\u7528\u673a\u7406<\/p>\n
\u91d1\u5c5e\u4e92\u5316\u7269\u50ac\u5316\u5242\uff0c\u5982LaNi5\u53ef\u50ac\u5316\u5408\u6210\u6c14\u8f6c\u5316\u4e3a\u70c3\uff0c\u662f70\u5e74\u4ee3\u5f00\u53d1\u7684\u4e00\u7c7b\u65b0\u578b\u50ac\u5316\u5242\uff0c\u4e5f\u662f\u78c1\u6027\u6750\u6599\u3001\u50a8\u6c22\u6750\u6599\uff1b\u91d1\u5c5e\u7c07\u72b6\u7269\u50ac\u5316\u5242\uff0c\u5982\u70ef\u70c3\u6c22\u919b\u5316\u5236\u7fb0\u57fa\u5316\u5408\u7269\u7684\u591a\u6838Fe3(CO)12\u50ac\u5316\u5242\uff0c\u81f3\u5c11\u8981\u6709\u4e24\u4e2a\u4ee5\u4e0a\u7684\u91d1\u5c5e\u539f\u5b50\uff0c\u4ee5\u6ee1\u8db3\u50ac\u5316\u5242\u6d3b\u5316\u5f15\u53d1\u6240\u5fc5\u9700\u3002\u8fd95\u7c7b\u91d1\u5c5e\u50ac\u5316\u5242\u4e2d\uff0c\u524d\u4e24\u7c7b\u662f\u4e3b\u8981\u7684\uff0c\u540e\u4e09\u7c7b\u572820\u4e16\u7eaa70\u5e74\u4ee3\u4ee5\u6765\u6709\u65b0\u7684\u53d1\u5c55\u3002<\/p>\n
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2\uff0e\u91d1\u5c5e\u548c\u91d1\u5c5e\u8868\u9762\u7684\u5316\u5b66\u952e<\/p>\n
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s\u8f68\u9053\u5f62\u6210s\u5e26\uff0cd\u8f68\u9053\u7ec4\u6210d\u5e26\uff0cs\u5e26\u548cd\u5e26\u4e4b\u95f4\u6709\u4ea4\u8fed\u3002\u8fd9\u79cd\u60c5\u51b5\u5bf9\u4e8e\u8fc7\u6e21\u91d1\u5c5e\u7279\u522b\u5982\u6b64\uff0c\u4e5f\u5341\u5206\u91cd\u8981\u3002s\u80fd\u7ea7\u4e3a\u5355\u91cd\u6001\uff0c\u53ea\u80fd\u5bb9\u7eb32\u4e2a\u7535\u5b50\uff1bd\u80fd\u7ea7\u4e3a5\u91cd\u7b80\u5e76\u6001\uff0c\u53ef\u4ee5\u5bb9\u7eb310\u4e2a\u7535\u5b50\u3002\u5982\u94dc\u7684\u7535\u5b50\u7ec4\u6001\u4e3a[Cu](3d10)(4s1)\uff0c\u6545\u91d1\u5c5e\u94dc\u4e2dd\u5e26\u7535\u5b50\u662f\u5145\u6ee1\u7684\uff0c\u4e3a\u6ee1\u5e26\uff1b\u800cs\u5e26\u53ea\u5360\u7528\u4e00\u534a\u3002\u954d\u539f\u5b50\u7684\u7535\u5b50\u7ec4\u6001\u4e3a[Ni] (3d5)(4s2)\uff0c\u6545\u91d1\u5c5e\u954d\u7684d\u5e26\u4e2d\u67d0\u4e9b\u80fd\u7ea7\u672a\u88ab\u5145\u6ee1\uff0c\u79f0\u4e3a\u201cd\u5e26\u7a7a\u7a74\u201d\u3002\u201cd\u5e26\u7a7a\u7a74\u201d\u7684\u6982\u5ff5\u5bf9\u4e8e\u7406\u89e3\u8fc7\u6e21\u91d1\u5c5e\u7684\u5316\u5b66\u5438\u9644\u548c\u50ac\u5316\u4f5c\u7528\u662f\u81f3\u5173\u91cd\u8981\u7684\uff0c\u56e0\u4e3a\u4e00\u4e2a\u80fd\u5e26\u7535\u5b50\u5168\u5145\u6ee1\u65f6\uff0c\u5b83\u5c31\u96be\u4e8e\u6210\u952e\u4e86\u3002<\/p>\n
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(3) \u914d\u4f4d\u573a\u6a21\u578b<\/p>\n
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