{"id":1675,"date":"2024-04-02T10:00:03","date_gmt":"2024-04-02T02:00:03","guid":{"rendered":"http:\/\/www.bdmaee.cn\/?p=1675"},"modified":"2024-04-02T10:00:03","modified_gmt":"2024-04-02T02:00:03","slug":"%e9%87%8d%e7%82%b9%e4%bb%8b%e7%bb%8d%e5%90%84%e7%b1%bb%e5%82%ac%e5%8c%96%e5%89%82%e7%9a%84%e7%bb%84%e6%88%90","status":"publish","type":"post","link":"http:\/\/www.bdmaee.cn\/archives\/1675","title":{"rendered":"\u91cd\u70b9\u4ecb\u7ecd\u5404\u7c7b\u50ac\u5316\u5242\u7684\u7ec4\u6210"},"content":{"rendered":"<p>\u91cd\u70b9\u4ecb\u7ecd\u5404\u7c7b<a href=\"http:\/\/www.bdmaee.cn\/\" target=\"_self\" 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mol\/wt\u6216m mol\/m2\u3002\u9178\u91cf\u4e5f\u53eb\u9178\u5ea6\uff0c\u6307\u9178\u7684\u6d53\u5ea6\u3002<\/p>\n<p>\u56fa\u4f53\u78b1\u7684\u5f3a\u5ea6\uff0c\u5b9a\u4e49\u4e3a\u8868\u9762\u5438\u9644\u7684\u9178\u8f6c\u53d8\u4e3a\u5171\u8f6d\u78b1\u7684\u80fd\u529b\uff0c\u4e5f\u5b9a\u4e49\u4e3a\u8868\u9762\u7ed9\u51fa\u7535\u5b50\u5bf9\u4e8e\u5438\u9644\u9178\u7684\u80fd\u529b\u3002\u78b1\u91cf\u7684\u8868\u793a\uff0c\u7528\u5355\u4f4d\u91cd\u91cf\u6216\u8005\u5355\u4f4d\u8868\u9762\u79ef\u78b1\u7684\u6beb\u6469\u5c14\u6570\uff0c\u5373m mol\/wt\u6216m 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= -11.9\uff0c\u6545\u56fa\u4f53\u9178\u5f3a\u5ea6H0 &lt; -11.9\u8005\u8c13\u4e4b\u56fa\u4f53\u8d85\u5f3a\u9178\u6216\u8d85\u9178\u3002<\/p>\n<p>\u56fa\u4f53\u8d85\u5f3a\u78b1\u662f\u6307\u5b83\u7684\u78b1\u5f3a\u5ea6\u7528\u78b1\u5f3a\u5ea6\u51fd\u6570H-\u8868\u793a\u9ad8\u4e8e+26\u8005\u3002\u56fa\u4f53\u8d85\u5f3a\u78b1\u591a\u4e3a\u78b1\u571f\u91d1\u5c5e\u6c27\u5316\u7269\uff0c\u6216\u78b1\u571f\u91d1\u5c5e\u4e0e\u78b1\u91d1\u5c5e\u7684\u590d\u5408\u6c27\u5316\u7269\u3002<\/p>\n<p>3.\u91cd\u8981\u7684\u56fa\u4f53\u9178\u78b1\u50ac\u5316\u5242<\/p>\n<p>\u78b1\u571f\u91d1\u5c5e\u6c27\u5316\u7269\u4e2d\u7684MgO\u3001CaO\u548cSrO2\u662f\u5178\u578b\u7684\u56fa\u4f53\u78b1\u50ac\u5316\u5242\u3002AlCl3\u3001FeCl3\u662f\u5178\u578b\u7684\u56fa\u4f53L\u9178\u50ac\u5316\u5242\u3002Al2O3\u6709\u591a\u79cd\u4e0d\u540c\u7684\u6676\u578b\u53d8\u4f53\u3002\u4f5c\u4e3a\u50ac\u5316\u5242\u6765\u8bf4\uff0c\u91cd\u8981\u7684\u662f\u03b3- Al2O3\u548c\u03b7- 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Al2O3\uff0c\u52a0\u6c22\u8131\u786b\u548c\u52a0\u6c22\u8131\u6c2e\u50ac\u5316\u5242\uff0c\u5c31\u662f\u7528Co\u6216\u8005Ni\u6539\u6027\u7684Al2O3- MoO3\u4e8c\u5143\u786b\u5316\u7269\u4f53\u7cfb\u3002Co-MoO3\/ Al2O3\u6216Ni-MoO3\/ Al2O3\u5728Al2O3\u4e2d\u539f\u6765\u53ea\u6709L\u9178\u4f4d\uff0c\u5c06MoO3\u5f15\u5165\u5f62\u6210\u4e86B\u9178\u4f4d\uff0cCo\u6216Ni\u7684\u5f15\u5165\u662f\u963b\u6b62L\u9178\u4f4d\u7684\u5f62\u6210\uff0c\u4e2d\u7b49\u5f3a\u5ea6\u7684L\u9178\u4f4d\u5728B\u9178\u4f4d\u5171\u5b58\u65f6\u6709\u5229\u4e8e\u52a0\u6c22\u8131\u786b\u7684\u6d3b\u6027\u3002L\u9178\u4f4d\u548cB\u9178\u4f4d\u5171\u5b58\uff0c\u6709\u65f6\u662f\u534f\u540c\u6548\u5e94\uff1b\u6709\u65f6L\u9178\u4f4d\u5728B\u9178\u4f4d\u90bb\u8fd1\u7684\u5b58\u5728\uff0c\u4e3b\u8981\u662f\u589e\u5f3aB\u9178\u4f4d\u5f3a\u5ea6\uff0c\u56e0\u6b64\u4e5f\u5c31\u589e\u52a0\u4e86\u5b83\u7684\u50ac\u5316\u6d3b\u6027\u3002\u6709\u7684\u53cd\u5e94\u867d\u4e0d\u4e3a\u9178\u6240\u50ac\u5316\uff0c\u4f46\u9178\u7684\u5b58\u5728\u4f1a\u5f71\u54cd\u53cd\u5e94\u7684\u9009\u62e9\u6027\u548c\u901f\u7387\u3002<\/p>\n<p>\u03b3- Al2O3\u8868\u9762\u6709\u5f3a\u9178\u90e8\u4f4d\u548c\u5f31\u9178\u90e8\u4f4d\uff1b\u5f3a\u9178\u4f4d\u662f\u50ac\u5316\u5f02\u6784\u5316\u53cd\u5e94\u7684\u6d3b\u6027\u90e8\u4f4d\uff0c\u5f31\u9178\u4f4d\u662f\u662f\u50ac\u5316\u8131\u6c34\u53cd\u5e94\u7684\u6d3b\u6027\u90e8\u4f4d\u3002\u56fa\u4f53\u9178\u50ac\u5316\u5242\u8868\u9762\u4e0a\u5b58\u5728\u4e00\u79cd\u4ee5\u4e0a\u7684\u6d3b\u6027\u90e8\u4f4d\uff0c\u662f\u5b83\u4eec\u7684\u9009\u62e9\u6027\u7279\u6027\u6240\u5728\u3002\u4e00\u822c\u6d89\u53caC-C\u952e\u65ad\u88c2\u7684\u53cd\u5e94\uff0c\u5982\u50ac\u5316\u88c2\u5316\u3001\u9aa8\u67b6\u5f02\u6784\u3001\u70f7\u57fa\u8f6c\u79fb\u548c\u6b67\u5316\u53cd\u5e94\uff0c\u90fd\u8981\u6c42\u5f3a\u9178\u4e2d\u5fc3\uff1b\u6d89\u53caC-H\u952e\u65ad\u88c2\u7684\u53cd\u5e94\u5982\u6c22\u8f6c\u79fb\u3001\u6c34\u5408\u3001\u73af\u5316\u3001\u70f7\u57fa\u5316\u7b49\uff0c\u90fd\u9700\u8981\u5f31\u9178\u4e2d\u5fc3\u3002<\/p>\n<p><img decoding=\"async\" class=\"alignnone size-full wp-image-1677\" src=\"http:\/\/www.bdmaee.cn\/wp-content\/uploads\/2024\/04\/1709215513550.png\" width=\"758\" height=\"439\" srcset=\"http:\/\/www.bdmaee.cn\/wp-content\/uploads\/2024\/04\/1709215513550.png 758w, http:\/\/www.bdmaee.cn\/wp-content\/uploads\/2024\/04\/1709215513550-300x174.png 300w\" sizes=\"(max-width: 758px) 100vw, 758px\" 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decoding=\"async\" class=\"alignnone size-full wp-image-1678\" src=\"http:\/\/www.bdmaee.cn\/wp-content\/uploads\/2024\/04\/1700901253354.png\" width=\"429\" height=\"431\" srcset=\"http:\/\/www.bdmaee.cn\/wp-content\/uploads\/2024\/04\/1700901253354.png 429w, http:\/\/www.bdmaee.cn\/wp-content\/uploads\/2024\/04\/1700901253354-300x300.png 300w, http:\/\/www.bdmaee.cn\/wp-content\/uploads\/2024\/04\/1700901253354-150x150.png 150w\" sizes=\"(max-width: 429px) 100vw, 429px\" \/><\/p>\n<p>\u5f0f\u4e2d\u548c\u5747\u4e3a\u5e38\u6570\uff0c\u5b83\u51b3\u5b9a\u4e8e\u53cd\u5e94\u7684\u8fd9\u7c7b\u548c\u6761\u4ef6\u3002<\/p>\n<p>\u5bf9\u4e8e\u78b1\u50ac\u5316\u7684\u53cd\u5e94\uff0c\u78b1\u50ac\u5316\u5e38\u6570\u5e94\u4e0e\u78b1\u7684\u79bb\u89e3\u5e38\u6570\u6210\u6bd4\u4f8b\u3002\u4e8c\u8005\u6709\u5982\u4e0b\u7684\u5173\u7cfb<\/p>\n<p>\u4ee5\u5e7f\u4e49\u9178\u50ac\u5316\u4f5c\u7528\u4e3a\u4f8b\uff0c\u4e00\u822c\u673a\u7406\u662f\uff1a\u53cd\u5e94\u7269S\u5148\u4e0e\u5e7f\u4e49\u9178HA\u4f5c\u7528\uff0c\u751f\u6210\u8d28\u5b50\u5316\u7269SH+\uff0c\u7136\u540e\u8d28\u5b50\u8f6c\u79fb\uff0c\u5f97\u5230\u4ea7\u7269P\uff0c\u5e76\u4ea7\u751f\u4e00\u4e2a\u65b0\u8d28\u5b50\uff0c<\/p>\n<p>SH+\u00a0 +\u00a0 H2O\u00a0 P\u00a0 +\u00a0 HO<\/p>\n<p>\u5176\u901f\u7387\u65b9\u7a0b\uff0c\u7531\u4e8e\u8d28\u5b50\u5316\u7269\u662f\u4e00\u4e2a\u6d3b\u6cfc\u7684\u4e2d\u95f4\u4f53\uff0c\u53ef\u7528\u7a33\u6001\u5904\u7406\u6cd5\uff0c\u5373(6.1.3)<\/p>\n<p>\u5f0f\u4e2d\uff0c\u7531\u4e8e\u662f\u7a00\u6eb6\u6db2\uff0c\u53ef\u4f5c\u4e3a\u5b9a\u503c\u3002\u53cd\u5e94\u901f\u7387\u4e3a<\/p>\n<p>(6.1.5)<\/p>\n<p>\u8fdb\u4e00\u6b65\u8003\u8651\u5e7f\u4e49\u9178HA\u7684\u89e3\u79bb\u5e73\u8861\uff0cHA + H2O = H3O+ + A-\uff0c(6.1.6)<\/p>\n<p>KHA\u4e3a\u89e3\u79bb\u5e73\u8861\u5e38\u6570\u3002\u4ee3\u5165\u5f0f\uff086.1.5\uff09\u5f97(6.1.7)<\/p>\n<p>\u8fd9\u5c31\u662f\u6240\u5f97\u7684\u901f\u7387\u65b9\u7a0b\uff0c\u53ef\u4ee5\u533a\u522b\u4e24\u79cd\u6781\u7aef\u7684\u60c5\u51b5\uff1a<\/p>\n<p>\u82e5k2 &gt;&gt; k-1cA-\uff0c\u5373k2cH+ &gt;&gt; k-1KHAcHA\uff0c\u4e2d\u95f4\u7269\u53cd\u5e94\u6781\u5feb<\/p>\n<p>(6.1.8)<\/p>\n<p>\u53cd\u5e94\u7531\u6b65\u9aa41\u63a7\u5236\uff0c\u901f\u7387\u6b63\u6bd4\u4e8e\u5e7f\u4e49\u9178\u7684\u6d53\u5ea6\uff0c\u662f\u6240\u8c13\u5e7f\u4e49\u9178\u50ac\u5316\u3002<\/p>\n<p>\u82e5k2 &lt;&lt; k-1cA-\uff0c\u4e2d\u95f4\u7269\u53cd\u5e94\u6781\u6162\uff0c\u53cd\u5e94\u7531\u6b65\u9aa42\u63a7\u5236\uff0c\u901f\u7387\u6b63\u6bd4\u4e8e\u6c22\u79bb\u6d53\u5ea6\uff0c\u662f\u6240\u8c13\u6c22\u79bb\u5b50\u50ac\u5316\u3002\u5728\u4e00\u5b9apH\u4e0b\u4e3a\u4e00\u7ea7\u53cd\u5e94\uff0c\u8517\u7cd6\u5728\u7a00\u9178\u6eb6\u6db2\u4e2d\u6c34\u89e3\u5373\u4e3a\u4f8b\u3002<\/p>\n<p>\u66f4\u5e7f\u6cdb\u7684\u8bf4\uff0c\u5e7f\u4e49\u9178HA\u548c\u6c22\u79bb\u5b50H+\u90fd\u6709\u5f71\u54cd\uff0c\u5e7f\u4e49\u78b1A-\u548c\u6c22\u6c27\u79bb\u5b50OH-\u4e5f\u6709\u4f5c\u7528\uff0c\u4e43\u81f3\u6ca1\u6709\u9178\u78b1\u50ac\u5316\u5242\u65f6\uff0c\u53cd\u5e94\u4e5f\u80fd\u6709\u4e00\u5b9a\u7a0b\u5ea6\u8fdb\u884c\u3002\u901f\u7387\u5e38\u6570\u53ef\u4ee5\u66f4\u4e00\u822c\u7684\u8868\u8fbe\u4e3a<\/p>\n<p>\u5f0f\u4e2d\u5373\u975e\u50ac\u5316\u53cd\u5e94\uff0c\u76f8\u5f53\u4e8e\u5f0f\uff086.1.9\uff09\u4e2d\u7684\uff0c\u76f8\u5f53\u4e8e\u5f0f\uff086.1.8\uff09\u4e2d\u7684\u3002\u6574\u4e2a\u53cd\u5e94\u901f\u7387\u5219\u4e3a<\/p>\n<p>\u5728\u7814\u7a76\u591a\u76f8\u9178\u78b1\u50ac\u5316\u53cd\u5e94\u673a\u7406\u548c\u901f\u7387\u65b9\u7a0b\u65f6\uff0c\u4e0a\u8ff0\u5206\u6790\u548c\u63a8\u5bfc\u53ef\u4ee5\u63d0\u4f9b\u501f\u9274\u4f5c\u7528\u3002<\/p>\n","protected":false},"excerpt":{"rendered":"<p>\u91cd\u70b9\u4ecb\u7ecd\u5404\u7c7b\u50ac\u5316\u5242\u200b\u7684\u7ec4\u6210 \u7ed3\u6784\u53ca\u5176\u50ac\u5316\u4f5c\u7528\u89c4\u5f8b\u4e0e\u50ac\u5316\u673a\u7406\u3002\u4e3b\u8981\u5305\u62ec\u4e94\u5927\u7c7b\u50ac\u5316\u5242\uff1a\u56fa\u4f53\u9178\u78b1\u50ac\u5316\u5242\uff0c\u5206\u5b50\u7b5b\u50ac\u5316\u5242\uff0c\u91d1\u5c5e\u50ac\u5316\u5242\uff0c\u91d1\u5c5e\u6c27\u5316\u7269\u548c\u91d1\u5c5e&#8230; <\/p>\n","protected":false},"author":2,"featured_media":1676,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[3],"tags":[],"class_list":["post-1675","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-news"],"_links":{"self":[{"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/posts\/1675"}],"collection":[{"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/users\/2"}],"replies":[{"embeddable":true,"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/comments?post=1675"}],"version-history":[{"count":1,"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/posts\/1675\/revisions"}],"predecessor-version":[{"id":1679,"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/posts\/1675\/revisions\/1679"}],"wp:featuredmedia":[{"embeddable":true,"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/media\/1676"}],"wp:attachment":[{"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/media?parent=1675"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/categories?post=1675"},{"taxonomy":"post_tag","embeddable":true,"href":"http:\/\/www.bdmaee.cn\/wp-json\/wp\/v2\/tags?post=1675"}],"curies":[{"name":"wp","href":"http:\/\/api.w.org\/{rel}","templated":true}]}}